Conductor composition V

ABSTRACT

A conductive composition consisting essentially of (a) 50-95 wt % finely divided particles of an electrically-conductive material dispersed in (b) a liquid vehicle, for use in the manufacture of an electrically-conductive pattern on a substrate for the use of reducing cross-sectional area and width while retaining conductivity and resistivity.

This application is a Continuation of Ser. No. 12/276,943 (filed Nov.24, 2008, now abandoned), which application is a Divisional of Ser. No.10/806,556 (filed Mar. 23, 2004, now U.S. Pat. No. 7,470,380).

FIELD OF THE INVENTION

The present invention relates to conductor compositions and their use inthe manufacture of components, particularly heating elements, inmicroelectronic circuits. These compositions are of particular use inthe manufacture of demisting elements in heated windows, for example, inautomotive glazing, particularly automotive backlights.

BACKGROUND OF THE INVENTION

The use of thick-film conductors as components in hybrid microelectroniccircuits is well known in the electronics field. An importantapplication of patterned electrically-conductive layers is in theautomobile industry, and particularly in the manufacture of windowswhich can be defrosted and/or demisted by an electrically-conductivegrid permanently attached to the window and capable of producing heatwhen powered by a voltage source. The conductive grid generallycomprises a series of tracks (or “hot-lines”) which are spaced regularlyacross one surface of the window, usually horizontally, between two“bus-bars” on opposing sides of the window, which are usually disposedvertically. The tracks and bus-bars are normally made from the samecomposition. Conductive compositions may also be used in various otherapplications, including printed circuits and heating elements generally,for instance, as base plates in hot water heating appliances. There is ageneral need within the electronics and electrical industry forlower-cost heating elements, particularly screen-printable heatingelements.

Conventional compositions for the manufacture of such components takethe form of a paste-like solid-liquid dispersion, where the solid phasecomprises finely divided particles of a noble metal or a noble metalalloy or mixtures thereof and an inorganic binder, dispersed into aliquid vehicle. The inorganic binder is typically a glass orglass-forming material, such as a lead silicate, and functions as abinder both within the composition and between the composition andsubstrate onto which the composition is coated. Due to environmentalconsiderations, the use of lead-containing binders is becoming lesscommon and lead-free binders such as zinc or bismuth borosilicates arenow often employed. The inorganic binder, also known as a frit, isconsidered a key component in conventional compositions.

Additional materials may be added in small quantities (generally lessthan about 3% by weight of the composition) to modify the properties ofthe composition and these include staining agents, rheology modifiers,resistivity modifiers, adhesion enhancers and sintering modifiers.

The consistency and rheology of the composition is adjusted to theparticular method of application which may comprise screen-printing,brushing, dipping, extrusion, spraying and the like. Typically,screen-printing is used to apply the composition. The pastes are usuallyapplied to an inert substrate, to form a patterned layer. The thick-filmconductor layer is normally dried and then fired, usually attemperatures between about 400 and 700° C., typically 600-700° C., tovolatilize or burn off the liquid vehicle and sinter or melt theinorganic binder and the metal components. Direct wet-firing, i.e.wherein the thick film layer is not dried before firing, has also beenused to generate the patterned layer.

In the manufacture of automotive backlights, there is typically anenamel layer coated around the periphery of the backlight, and it is inthis area which the bus-bars are normally printed. As used herein, theterm “enamel” refers to the layer applied to the surface of a substrate(typically glass) or part thereof onto which a conductor composition isapplied. The enamel is a dispersion of a glass or glass-forming frit orbinder (as described herein) in powder form in an organic carriervehicle, normally with additional fillers and/or opacifiers and/orcolorants. The enamel is typically colored black in order to provide anobscuration band around the periphery of the backlight. This is doneprimarily to provide protection against UV attack by sunlight on theadhesive that is used to glue the backlight into the car, but also forcosmetic or decorative purposes. The glass powder of the enamel isdesigned to soften and flow at the firing temperatures of the backlightto form a film that adheres to the surface of the substrate. Therheological characteristics of the enamel are determined in advancedepending on the selected firing temperature of the backlight.

In practice, firing to effect sintering of the conductive pattern iseffected in the same stage of manufacture as the firing of the backlightto shape it into its desired form and the firing to effect sintering ofthe enamel. The process of manufacture therefore comprises the followingsteps:

-   -   printing the enamel composition onto the glass substrate,        typically by a screen-printing technique, and then curing the        composition by UV-radiation or drying at about 100-200° C. to        drive off the solvent;    -   (ii) printing the conductive composition and optionally drying        to drive off solvent; and    -   (iii) firing the coated glass substrate to effect sintering of        the layers and forming of the backlight, optionally with a rapid        cooling step to produce a toughened glass substrate, in        accordance with conventional methods known in the art.

It is also necessary to connect the conductive pattern to the othercomponents of the electronic circuit, such as the power source, resistorand capacitor networks, resistors, trim potentiometers, chip resistorsand chip carriers. This is generally achieved by using metal clips,typically comprising copper, which are soldered either directly adjacentto or on top of the conductive layer, usually in the bus-bar sections ofthe pattern. Where the clips are soldered on top of the conductivelayer, attachment is either directly onto the conductive pattern itselfor onto a solderable composition which is overprinted onto the pattern(an “over-print”). An over-print is generally applied only in the regionof the conductive pattern to which the metal clips are attached bysolder, which region is generally referred to as the “clip area”. Theability to solder onto the electrically-conductive layer is an importantparameter in the manufacture of heating elements since it removes therequirement for an over-print. However, the inorganic binder, which isimportant for binding the paste onto the substrate, can interfere withsolder wetting and result in poor adhesion of the soldered metal clipsto the conductive layer. The requirements of high substrate adhesion andhigh solderability (or adhesion of the metal clips to the conductivepattern) are often difficult to meet simultaneously. It is particularlyimportant to ensure high substrate adhesion in the clip area since it isthis area of the conductive pattern that is subjected to the moststress.

It is desired to decrease the visibility of the conductive pattern onthe automotive backlight, particularly by decreasing the width of theconductive strips that form the conductive pattern. Typically the widthof the conductive strips is about 1 mm in conventional demistingelements. In addition, it is also desired to maintain a highconductivity and low resistivity. However, it is not desirable tosignificantly increase the height of the conductive pattern above thesurface of the glass backlight, which in conventional backlights istypically about 10 μm. It is therefore desired to reduce thecross-sectional area while retaining conductivity, and one way ofachieving this is to increase the fired density of the material in theconductive pattern.

However, there is an upper limit to the concentration of solids for aconductive paste, which is suitable for manufacture of a conductivepattern. When the amount of solids in the dispersion exceeds this limit,the paste becomes difficult to handle in the processes used tomanufacture the pattern. Moreover, an increased solids fraction incompositions comprising a conductive component and a frit component inconventional proportions has been found to lead to cracking of theenamel during the firing stage of the manufacture of the backlight.

It is an object of this invention to provide an economicalelectrically-conductive coating composition suitable for the manufactureof an electrically-conductive pattern, particularly a pattern havingnarrower width tracks, which exhibits good adhesion to the substrate andavoids or minimizes one or more of the above-mentioned disadvantages,particularly cracking of the enamel on an enamel-coated substrate. It isa further object of this invention to provide an economicalelectrically-conductive coating composition suitable for the manufactureof an electrically-conductive pattern, particularly a pattern havingnarrower width tracks, which exhibits good adhesion to the substratewhilst minimizing the cracking of the enamel, and which exhibits highconductivity and low resistivity.

DETAILED DESCRIPTION OF THE INVENTION

Accordingly, the present invention provides a composition suitable foruse in the manufacture of an electrically-conductive pattern, saidcomposition comprising finely divided particles of anelectrically-conductive material dispersed in a liquid vehicle, whereinan inorganic binder in said composition is present at less than 1.0%,preferably less than 0.8%, preferably less than 0.5%, preferably lessthan 0.3%, preferably less than 0.1% of the total solids in thecomposition and is preferably absent from said composition.

It has unexpectedly been found that it is not necessary to utilize aninorganic binder in the conductive composition in order to achieve goodadhesion, particularly to an enamel-coated substrate, and that areduction in the amount of inorganic binder avoids or minimizes thecracking of enamel. Such compositions are suitable for manufacturingconductive patterns having tracks of a reduced cross-sectional area andwidth whilst retaining high conductivity and low resistivity.

The compositions described herein are suitable for use as pastecompositions for forming thick-film conductive patterns on a substrate,for instance, by the process of screen-printing. The compositions of thepresent invention are of particular use as components in the manufactureof windows that can be defrosted and/or demisted by anelectrically-conductive grid attached to the window, particularly foruse in automotive industry.

As used herein, the term “finely divided” is intended to mean that theparticles are sufficiently fine to pass through a 325-mesh screen (USstandard sieve scale). It is preferred that at least 50%, preferably atleast 90%, and more preferably substantially all of the particles are inthe size range of 0.01 to 20 μm. Preferably, the largest dimension ofsubstantially all particles is no more than about 10 μm and desirably nomore than about 5 μm.

As used herein, the term “inorganic binder” refers to any material,which upon sintering serves to bind the metal to a substrate such as aglass (including toughened and laminated glass), enamel, enamel-coatedglass, ceramic, alumina or metal substrate. The binder generally has asoftening point of between about 350 and 620° C. in order that thecompositions can be fired at the desired temperatures (typically 400 to700° C., particularly 580 to 680° C.) to effect sintering, wetting andadhesion to the substrate. Examples of inorganic binders include leadborates; lead silicates; lead borosilicates; cadmium borate; leadcadmium borosilicates, zinc borosilicates; sodium cadmium borosilicates;bismuth silicates; bismuth borosilicates; bismuth lead silicates;bismuth lead borosilicates; oxides or oxide precursors of metals such aszinc, cobalt, copper, nickel, manganese or iron.

The electrically-conductive particles can be in any form suitable forthe production of the compositions of the present invention. Forexample, electrically-conductive metallic particles may bin in the formof either metal powders or metal flakes or blends thereof. In oneembodiment of the invention, the metallic particles are a blend ofpowder and flake. The particle size of the metal powder or flake is notby itself narrowly critical in terms of technical effectiveness.However, particle size does affect the sintering characteristics of themetal in that large particles sinter at a lower rate than smallparticles. Blends of powders and/or flakes of differing size and/orproportion can be used to tailor the sintering characteristics of theconductor formulation during firing, as is well-known in the art. Themetal particles should, however, be of a size that is appropriate to themethod of application thereof, which is usually screen printing. Themetal particles should therefore generally be no larger than about 20 μmin size and preferably less than about 10 μm. The minimum particle sizeis normally about 0.1 μm.

The metals used for the electrically-conductive material are typicallyselected from silver, gold, platinum and palladium. The metal can beused either in isolation or as a mixture that forms an alloy uponfiring. Common metal mixtures include platinum/gold, palladium/silver,platinum/silver, platinum/palladium/gold and platinum/palladium/silver.The electrically-conductive material may also comprise other metals suchas tin, aluminum, zinc, copper, cobalt, nickel, iron, and bismuth,either in the form of metallic particles or in the form of particles ofan alloy containing such metal(s) or in the form of a derivative whichis substantially converted to the metal under the action of heat. In oneembodiment, the metals are selected from silver, optionally mixed withpalladium, platinum and/or gold, and preferably from silver andsilver/palladium. The preferred metal for the electrically-conductivematerial is silver. Thus, the electrically conductive componentpreferably comprises at least 90%, preferably at least 95%, preferablyat least 98%, preferably at least 99% by weight silver, and preferablysubstantially all of the electrically-conductive component is silver. Itis preferred that the compositions contain at least 50% weight silverparticles larger than 1.0 μm.

The size of the particles should generally be no larger than about 20 μmand preferably less than 10 μm. The particles may be spherical orspheroid or irregular in shape, in the form of a flake or a powder, orin any other suitable morphology.

In order to facilitate the transfer of the electrically-conductivematerial onto the substrate, it is dispersed into a liquid vehicle toform a semi-fluid paste, which is then printed in a desired circuitpattern. The liquid vehicle may be an organic medium or may beaqueous-based. Preferably the liquid vehicle is an organic medium. Anysuitably inert liquid can be used as an organic medium. The liquidvehicle should provide acceptable wettability of the solids and thesubstrate, a relatively stable dispersion of particles in the paste,good printing performance, dried film strength sufficient to withstandrough handling, and good firing properties. Various organic liquids withor without thickening agents, stabilizing agents and/or other commonadditives are suitable for use in the preparation of the compositions ofthe present invention. Exemplary of the organic liquids which can beused are alcohols (including glycols); esters of such alcohols such asthe acetates, propionates and phthalates, for instance dibutylphthalate; terpenes such as pine oil, terpineol and the like; solutionsof resins such as polymethacrylates of lower alcohols; or solutions ofethyl cellulose in solvents such as pine oil and monobutyl ether ofdiethylene glycol. The vehicle can also contain volatile liquids topromote fast setting after application to the substrate.

A preferred organic medium is based on a combination of a thickenerconsisting of ethyl cellulose in terpineol (typically in a ratio of 1 to9), optionally combined for instance with dibutyl phthalate or with themonobutyl ether of diethylene glycol (sold as butyl Carbitol™). Afurther preferred organic medium is based on ethyl cellulose resin and asolvent mixture of alpha-, beta- and gamma-terpineols (typically 85-92%alpha-terpineol containing 8-15% beta and gamma-terpineol).

The compositions described herein may additionally comprise furtheradditives known in the art, such as colorants and staining agents,rheology modifiers, metallic resistivity modifiers, adhesion enhancers,sintering inhibitors, green-state modifiers, surfactants and the like.

In a preferred embodiment, the electrically-conductive materialcomprises at least 95%, preferably at least 96%, preferably at least97%, preferably at least 98%, more preferably at least 99%, andpreferably substantially all of the solid phase material use dot preparethe compositions of the invention.

The ratio of liquid vehicle to solids in the dispersion is in partdetermined by the final desired formulation viscosity which, in turn, isdetermined by the printing requirements of the system. Normally, inorder to achieve good coverage, the dispersions will contain about 50 toabout 95%, preferably about 70 to about 95%, more preferably from about80 to about 95%, and more preferably from about 85 to about 95% byweight solids, and about 5 to 50% by weight liquid vehicle.

In the preparation of the compositions described herein, the particulatesolids are mixed with the liquid vehicle and dispersed with suitableequipment, such as a three-roll mill or a power-mixer, according toconventional techniques well-known in the art, to form a suspension. Theresulting composition has a viscosity generally in the range of about10-500, preferably in the range of about 10-200, more preferably in therange of about 15-100 Pa·s at a shear rate of 4 sec⁻¹, for instance, asmeasured on a Brookfield HBT viscometer using a utility cup and a No. 14spindle at 10 rpm and 25° C. The general procedure for preparing thecompositions described herein is set out below.

The ingredients of the paste are weighed together in a container. Thecomponents are then vigorously mixed by a mechanical mixer to form auniform blend; then the blend is passed through dispersing equipment,such as a three-roll mill, to achieve a good dispersion of particles toproduce a paste-like composition having a suitable consistency andrheology for application onto a substrate, for instance byscreen-printing. A Hegman gauge is used to determine the state ofdispersion of the particles in the paste. This instrument consists of achannel in a block steel that is 25 μm deep (1 mil) on one end and rampsup to zero depth at the other end. A blade is used to draw down pastealong the length of the channel. Scratches appear in the channel wherethe agglomerates' diameter is greater than the channel depth. Asatisfactory dispersion will give a fourth largest scratch point oftypically 1-18 μm. The point at which half of the channel is uncoveredwith a well-dispersed paste is between 3 and 8 μm typically. Fourthscratch measurements of >20 μm and “half-channel” measurements of >10 μmindicate a poorly dispersed suspension.

The compositions are then applied to a substrate using conventionaltechniques known in the art, typically by the process of screenprinting, to a wet thickness of about 20-60 μm, preferably about 35-50μm. The compositions described herein can be printed onto the substrateseither by using an automatic printer or a hand printer in theconventional manner. Preferably, automatic screen printing techniquesare employed using screens with at least 45 yarns/cm, and preferably atleast 77 yarns/cm. The printed pattern is optionally dried at below 200°C., preferably at about 150° C., for a time period between about 30seconds to about 15 minutes before firing. Firing to effect sintering ofthe particles is preferably done in a well-ventilated belt conveyorfurnace with a temperature profile that will allow burn-off of thevehicle at about 200° C.-500° C., followed by a period of maximumtemperature of about 500-1000° C., preferably about 600-850° C., lastingfor about 30 seconds to about 15 minutes. This is followed by a cooldowncycle, optionally a controlled cooldown cycle, to preventover-sintering, unwanted chemical reactions at intermediate temperaturesor substrate fracture, which can occur from too rapid cooldown. Theoverall firing procedure will preferably extend over a period of about2-60 minutes, with about 1-25 minutes to reach the firing temperature,about 10 seconds to abut 10 minutes at the firing temperature and about5 seconds to 25 minutes in cooldown. For the manufacture of a toughenedglass substrate, a controlled cooldown cycle is generally used whereinthe overall firing procedure typically extends over a period of about 2to 5 minutes, with about 1 to 4 minutes to reach the firing temperature,followed by a rapid cooldown.

Typical thicknesses of the thick-films after firing are from about 3 μmto about 40 μm, preferably from about 8 μm to about 20 μm, morepreferably from about 5 to 15 μm, and typically about 10 μm. Typicalwidths of the individual tracks in the conductive pattern after firingare 1 mm or less, preferably 400 μm or less, more preferably 300 μm orless, and more preferably 250 μm or less.

The compositions described herein are primarily intended for use in themanufacture of heating elements in windows such a defogging ordefrosting elements in automotive glazing, particularly backlights. Inorder for the window to defrost quickly, the circuit must be capable ofsupplying large amounts of power from a low voltage power source,typically 12 volts. For such power sources the resistivity requirementof the conductive pattern is generally in the range of from about 1.5 toabout 15 μΩ cm, preferably from about 1.5 to about 4 μΩ cm.

The compositions may also be used to incorporate other conductivefunctions into the window, such as a printed aerial or antenna. Thecoating compositions can be employed in various other applications,including printed circuits and heating elements generally. For instance,the compositions described herein may be used as base plates in hotwater heating appliances.

According to a further aspect of the invention there is provided aprocess for the manufacture of an electrically-conductive pattern, saidprocess comprising:

-   -   (i) providing a substrate;    -   (ii) providing on at least a part of said substrate a layer of        enamel, and optionally curing or drying the enamel as described        herein;    -   (iii) applying onto said enamel a conductive composition        comprising finely divided particles of an        electrically-conductive material dispersed in a liquid vehicle,        wherein an inorganic binder in said composition is present at        less than 1.0%, preferably less than 0.8%, preferably less than        0.5%, preferably less than 0.3%, preferably less than 0.1% of        the total solids in the composition and is preferably absent        from said composition, and optionally drying said conductive        composition;    -   (iv) firing the coated substrate.

Preferably, the process for depositing said enamel and/or saidelectrically conductive composition is a screen-printing process.

The substrate is typically a rigid substrate such as glass. The firingprocess may optionally include a rapid cool-down stage for themanufacture of toughened glass.

According to a further aspect of the present invention there is provideda substrate having on at least a part thereof a layer of enamel, and onat least a part of said enamel an electrically-conductive pattern, saidcomposition comprising finely divided particles of anelectrically-conductive material dispersed in a liquid vehicle, whereinan inorganic binder in said composition is present at less than 1.0%,preferably less than 0.8%, preferably less than 0.5%, preferably lessthan 0.3%, preferably less than 0.1% of the total solids in thecomposition and is preferably absent from said composition.

According to a further aspect of the invention, there is provided use ofthe conductive composition described herein in the manufacture of anelectrically conductive pattern.

The following procedures are used to evaluate the compositions describedherein.

Adhesion

Copper clips (obtained from Quality Product Gen. Eng. (Wickwar), UK) aresoldered to the fired conductive pattern on a glass substrate(dimensions 10.2 cm×5.1 cm×3 mm) using a 70/27/3 Pb/Sn/Ag solder alloyat a soldering iron temperature of 350 to 380° C. A small quantity of amildly active rosin flux, such as ALPHA 615-250® (Alpha Metals Limited,Croydon, U.K.) may be used to enhance solder wetting and to keep thesolder and clip in place during assembly of parts, in which case theflux is applied to the solder using a shallow tray containing a thinfilm of fresh flux. Adhesion is measured on a Chattillon® pull testerModel USTM at a pull speed of 0.75±0.1 inches per minute (1.91±0.25 cmper minute) and the pull strength recorded at adhesion failure. Theaverage value of adhesion failure over 8 samples is determined. Theadhesion should preferably be greater than 10 kg, more preferablygreater than 15 kg and more preferably greater than 20 kg.

Resistance and Resistivity

The resistance of the fired conductive pattern on a glass substrate(dimensions 10.2 cm×5.1 cm×3 mm) is measured using a GenRad Model 1657RLC bridge calibrated for use between 1 and 900Ω or equivalent. Thethickness of the conductive layer is measured using a thicknessmeasuring device such as a surf-analyzer (e.g. TALYSURF (a contactmeasuring device which analyzes the substrate surface in 2 dimensionsusing a spring loaded stylus; any change in height deflects the stylus,which is registered on a recorder, such as a chart recorder; thedifference between the base line and average height gives the printthickness). Resistance of the pattern is determined by placing the probetips at the point where the conductive track meets the solder pads. Thebulk resistivity (thickness-normalized) of the layer is determined bydividing the measured resistance for the pattern by the number ofsquares therein where the number of squares is the length of theconductive track divided by the width of the track. The resistivityvalue is obtained as mΩ/square at a normalized thickness, herein 10 μm,and presented herein in the units of μΩ cm.

Particle Size

The state of dispersion of the paste during manufacture is measuredaccording to ASTM D1210-79 using a large Hegman type fineness of grindgauge. The particle size distribution of the conductive particles ismeasured using a Microtrac™ II Particle Size Analyser Model 7997 (Leedsand Northrop) and the d50 value calculated (i.e. the size below which50% of the particles lie).

The invention will now be described with reference to the followingexamples. It will be appreciated that the examples are not intended tobe limiting and modification of detail can be made without departingfrom the scope of the invention.

EXAMPLES

Conductive patterns were prepared using the method hereinbeforedescribed. The silver particles were a mixture of 66% irregular-shapesilver particles (d50=5.4 to 11 μm), 11% spherical silver particles(d50=0.4 to 0.9 μm) and 11% flake silver particles (d50 of approximately2.0 μm). The binder used was a composition comprising Bi₂O₃ (69.82%),B₂O₃ (8.38%), SiO₂ (7.11%), CaO (0.53%), ZnO (12.03%) and Al₂O₃ (2.13%).The liquid vehicle was comprised primarily of ethyl cellulose interpineol (in a ratio of 1 to 9) combined with the monobutyl ether ofdiethylene glycol (sold as butyl Carbitol™ for rheology adjustment. Thesubstrate was a glass substrate coated with Cerdec 14252 enamel (Cerdec,NL; Ferro (Holland) BV, NL). All parts were fired through a belt furnacewith a peak firing temperature of 660° C., with the samples spendingapproximately 72 s at peak temperature. The total door-to-door transittime in the furnace was approximately 21 minutes. The fired filmthickness is shown in Table 1 below.

TABLE 1 Example 1 Comparative Example 1 Silver content (%) 94 88 Bindercontent (%) 0 4 Organic content (%) 6 8 Fired film thickness (μm) 40 35Resistance (μΩ cm) 0.91 1.05 Resistivity (mΩ/square) 3.64 3.68 Adhesion(Kg) 34.5 32 Cracking of enamel Did not crack Cracked

1. A conductive composition comprising: (a) finely divided particles ofan electrically-conductive material, wherein the electrically conductivematerial comprises silver and aluminum; (b) an inorganic binder;dispersed in (c) a liquid vehicle wherein the total composition contains50-95% by weight solids, and wherein said inorganic binder is present atless than 1% of the total solids in the composition.
 2. The compositionof claim 1, wherein the inorganic binder is lead-free.
 3. Thecomposition of claim 1, wherein two or more metals are combined to forma metals composition or alloy.
 4. The composition of claim 1, whereinthe electrically-conductive material is a metal in the form of one ormore components selected from the group consisting of: metallicparticles, alloys comprising the metal, and derivatives substantiallyconverted to the metal under the action of heat.
 5. The composition ofclaim 1, wherein the electrically-conductive material further comprisesnickel.
 6. The composition of claim 1, wherein theelectrically-conductive material is in the form of metal powders, metalflakes, or blends thereof.
 7. The composition of claim 1, wherein theviscosity is 10-500 Pa·s at a shear rate of 4 sec⁻¹.
 8. The compositionof claim 1, wherein the liquid vehicle comprises diethylene glycol, amonobutyl ether of diethylene glycol, or a mixture thereof.
 9. Theconductive composition of claim 1, wherein the electrically conductivematerial comprises at least 90 wt % silver.
 10. The conductivecomposition of claim 1, wherein the inorganic binder is present at lessthan 0.8% of the total solids in the composition.